PEROXIDE - FTC Korea

Home > Buy Now > Pigment > PEROXIDE

Product Information

visitors: 1935

FTC Korea
[Korea]

Address:
982 Yongso-ri Yanggam-myun Hwasung-si Gyeonggi-do 445-933 Korea

Phone:
82-31-3859990

Contact name:
Insun Kim , Director

Product Information

	PEROXIDE

Click to enlarge image

* For more information, click product name.

ALKENOX-P100

ALKENOX P-100

Summary

ALKENOX P-100 is a white fine powder which has peroxy group in the molecular. It is generally used for initiator of polymerization in the unsaturated polyester resin, vinyl chloride
mono-polymerization & Copol ymerization.

Formula

- Formula :

- Name : Bis-(4-tert-butylcyclohexyl)
Peroxy dicarbonate
- CAS No : 15520-11-3
- Molecular weight : 398.64

Pyhsical Properity

- Appearance : White fine power
- Purity : Min. 95%
- Molecular weight : 398.64
- Temperature at 10 hrs half life : 44℃
- Activation energy : 30.2kcal / mol
- Solubility : insoluble in water,
- Soluble in Ketones, Esters, Aromatic
Hydrocarbon

Chemical Prooerity

- Strong oxidation agent. - Active oxygen content : Min 3.8% - Heat decomposition properties Half life of ALKENOX P-100 at 0.2 mol/mol in benzene
Temp (℃)	Half life(hours)
40	17.4
44	10
50	4
60	1
92	1
- Flash point : Room temperature - Combustion properties (sample 10g) Burning time : 5 sec Flame length : 100㎝

Decomposition Compound

ALKENOX P-100 is easy to decompose by hea The Mechanism of decomposition.

Safety Test

- Ignition temp. : Room temp
- Auto lgnition temp : 360℃
- Combustion properties (sample 10g)
  Combustion time : 5 sec
  Length of flame : 100 sec
  Drop-hammer sensitivity : 30Cm
  Pressure test : Max.0.7mm

Package

- Inner package : Polyethylene bag
- Ourter package : Craft paper box

Application

-The initiator of unsaturated polyester resin
ALKENOX P-100 has low decomposing temp(44℃). It is suitable for pulltrusion mold, continuous laminating and large scale mold. Especially large scale moding, heating furnace is needed to get a high temperature. ALKENOX P-100 which has low decomposing temp is suitable for that cases. ALKENOX P-100 is also used with other curing agent such as BPO(Benzoxl peroxide), TBPB(t-butyl-perbenzoate) and other metal salt accelerators. In that case, we can expect a improved properties after curing.

- Polymerization initiator of VCM(Vinyl Chloride Monomer)
ALKENOX P-100 is used for polymerization of VCM which is the monomer of PVC at 40~70℃

- Polymerization initiator of other monomer
ALKENOX P-100 is used as initiator of homopolymer
- ization & copolymerization of acrylate, methacrylate

ane vinylidene floride monomer-

Storage and Handling

The test report of storage safety of ALKENOX P-100

Period of storage	Decrease rate of active oxygen
Period of storage	30℃	40℃
1 week	-	1.5%
2 weeks	1.3%	2.6%
3 weeks	-	4.6%
4 weeks	1.3%	-
5 weeks	-	7.4%
6 weeks	2%	13%
7 weeks	3%	-
11 weeks	4.3%	-
24 weeks	6.4%	-

- Storage
   ALKENOX P-100 is quite active peroxide. However handling it at room temperature is possible as it's storage stability at room temperature is a rather high so it is possible to handle at room temperature.   But it can be decompesed at above 25℃, so it must be stored under 20℃ and kept away from direct sunligiht

- First aid
   Skin contact cause a hazard like other peroxides, so appropriate protection is needed. During working, protective clothes and protective hand cream is needed.
---Eye Contact : Immediately flush eyes with plenty of water.
Get medical attention immddiatly

---Skin Contact : Immediately flush skin with   plenty of soap and water. Get medical attention immediately.

---Ingestion : Not to vomit. Get medical attention
- Toxicological information
   Oral rat : LD 50 : >5g/㎏

Appendix

- Solublity Data (wt% conc)

Solvents	-20℃	0℃	10℃	20℃	30℃
Methanol	-	1	-	-	2.3
Hentane	-	7.5	-	-	17.5
Shellsol T	-	2	-	4.04	-
Shellsol K	-	-	-	5	-
MEK	11	24.7	-	-	31.4
MIBK	-	17.5	-	-	31.3
Benzene	-	29.3	46.7	-	49.3
Tpluene	-	33	-	-	49
MeAc	-	11.5	-	-	22.2
FtAc	-	16	-	-	32
Dibuth Phthalate	-	9.2	-	11.8	14.1
CCI4	-	19	-	-	21.5
Ethylene	-	-	-	-	-
teichloride	11	24.5	-	33	-
Viryl	-	-	-	-	-
Chloride	15	25	-	-	-
MMA	-	19.8	-	25	-

- Curing Properties & Pot life of curing agent

Initiator	Criti Cal Temp (℃)	80℃				Pot Life (hrs)
Initiator	Criti Cal Temp (℃)	G.T (min	C.T (min	T.max (℃)	Hard ness	30℃	40℃
ALKENOXP-100	50	0.6	1.1	231	47	10	3
Kayanox		1.6	2.8	209	42	3	1
Laubox		3	4.1	204	44	35	8
Trigonox 38	65	4	11.3	173	42	9	3
BPO	70	5.9	7.3	203	44	50	14
t-butyl perhenzoate	70	3.7	5.2	222	48	27	8
Trigonox 29~75%	70	8.4	10.7	200	47	70	22
Kayacarhon BIC-75	70	16.9	26.2	193	45	40	18
Kayanox A-M	80	3.3	6.3	197	43	70	3

Initiator	Criti Cal Temp (℃)	100℃				Pot Life (hrs)
Initiator	Criti Cal Temp (℃)	G.T (min)	C.T (min)	T.max (℃)	Hard ness	30℃	40℃
ALKENOXP-100	50	-	-	-	-	10	3
Kayanox		0.2	0.6	226	43	3	1
Laubox		0.3	0.7	210	45	35	8
Trigonox 38	65	1.5	2.9	229	46	9	3
BPO	70	1	15	248	47	50	14
t-butyl perhenzoate	70	0.2	0.5	223	50	27	8
Trigonox 29~75%	70	1.6	2.3	222	48	70	22
Kayacarhon BIC-75	70	2.9	4.2	237	45	40	18
Kayanox A-M	80	0.8	0.8	226	4.	70	3

※ Test Condition : JISK 6901, use unsaturated
polyester resin lnitiator : 1phr

- The combination of ALKENOXP-100 & other initiator

t-butyl perhenzoate

Using amount(phr)		80℃ Curing				Pot life (hrs)
ALKENOX P-100	t-butyl perhenzoate	G.T (min)	C.T (min)	T.max (℃)	Hard ness	Pot life (hrs)
0	1	3.8	5.2	222	45	26
0.2	0.8	2	2.9	224	45	16
0.5	0.5	1	1.6	221	45	11
0.8	0.2	0.6	1.2	223	45	9
1	0	0.5	0.9	226	45	8

BPO

Using amount(phr)		80℃ Curing				Pot life (hrs)
ALKENOX P-100	t-butyl perhenzoate	G.T (min)	C.T (min)	T.max (℃)	Hard ness	Pot life (hrs)
0	1	5.9	7.3	220	45	4~5
0.2	0.8	2.4	3.3	222	45	27
0.5	0.5	1	1.7	225	45	13
0.8	0.2	0.6	1.2	223	45	9
1	0	0.5	0.5	226	45	8